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Chemical-electric energy conversion effect in zirconia nanopowder systems

A. S. DoroshkevichDonetsk Institute for Physics and Engineering named after A.A. Galkin, National Academy of Sciences of Ukraine, Kyiv, 03680, UkraineAndriy I. LyubchykCENIMAT, Department of Materials Science, Faculty of Science and Technology, Universidade NOVA de Lisboa and CEMOP/UNINOVA, Campus de Caparica, 2829-516, Caparica, PortugalА. В. ШилоDonetsk Institute for Physics and Engineering named after A.A. Galkin, National Academy of Sciences of Ukraine, Kyiv, 03680, UkraineT. Yu. ZelenyakDubna State University, Dubna, Moscow oblast, 141982, RussiaV. A. GlazunovaState Institution “Donetsk Institute for Physics and Engineering named after A.A. Galkin”, Donetsk, 83114, UkraineV. V. BurhovetskiyState Institution “Donetsk Institute for Physics and Engineering named after A.A. Galkin”, Donetsk, 83114, UkraineA. V. SaprykinaDonetsk Institute for Physics and Engineering named after A.A. Galkin, National Academy of Sciences of Ukraine, Kyiv, 03680, UkraineKh. T. HolmurodovDubna State University, Dubna, Moscow oblast, 141982, RussiaI. K. NosolevDonetsk Institute for Physics and Engineering named after A.A. Galkin, National Academy of Sciences of Ukraine, Kyiv, 03680, UkraineV. S. DoroshkevichDonetsk National University, Donetsk, 83001, UkraineГ. К. ВолковаDubna State University, Dubna, Moscow oblast, 141982, RussiaTetyana KonstantinovaDonetsk Institute for Physics and Engineering named after A.A. Galkin, National Academy of Sciences of Ukraine, Kyiv, 03680, UkraineV. I. BodnarchukJoint Institute for Nuclear Research, Dubna, Moscow Region, 141980, RussiaP. P. GladyshevDubna State University, Dubna, Moscow oblast, 141982, RussiaВ. А. ТурченкоJoint Institute for Nuclear Research, Dubna, Moscow Region, 141980, RussiaS. A. SinyakinaDonetsk Institute for Physics and Engineering named after A.A. Galkin, National Academy of Sciences of Ukraine, Kyiv, 03680, Ukraine
2017en
ABI

Аннотация

Issues concerned with the energy conversion of exothermal heterophase processes are discussed using the physico-chemical interaction between ZrO2–Y2O3 (3 mol %) nanopowder system and atmospheric moisture as an example. The electrical properties of an experimental sample are investigated upon moisture saturation in the case of a molecular-flow density gradient. A probable mechanism for the effect based on the theory of contact phenomena in semiconductors is proposed. The idea of developing chemical-electric converters fabricated from nanoscale materials with dielectric conduction is suggested.

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