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A review on latest trends in cleaner biodiesel production: Role of feedstock, production methods, and catalysts

Pranjal MaheshwariDepartment of Chemical Engineering and Biochemical Engineering, Rajiv Gandhi Institute of Petroleum Technology, Amethi, Jais, 229304, Uttar Pradesh, IndiaMohd Belal HaiderDepartment of Chemical Engineering and Biochemical Engineering, Rajiv Gandhi Institute of Petroleum Technology, Amethi, Jais, 229304, Uttar Pradesh, IndiaMohammad YusufDepartment of Chemical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 32610, Perak, MalaysiaJiří Jaromír KlemešSustainable Process Integration Laboratory, SPIL, NETME Centre, Faculty of Mechanical Engineering, Brno University of Technology, VUT Brno, Technická 2896/2, 616 00, Brno, Czech RepublicAwais BokhariDepartment of Chemical Engineering, COMSATS University Islamabad (CUI), Lahore Campus, 54000, Punjab, Lahore, PakistanMukarram BegDepartment of Petroleum Engineering, University Institute of Engineering, Chandigarh University, Mohali, 140413, Punjab, IndiaAmani Al–OthmanDepartment of Chemical Engineering, American University of Sharjah, PO. Box 26666, Sharjah, United Arab EmiratesRakesh KumarDepartment of Chemical Engineering and Biochemical Engineering, Rajiv Gandhi Institute of Petroleum Technology, Amethi, Jais, 229304, Uttar Pradesh, IndiaAmit K. JaiswalEnvironmental Sustainability and Health Institute, Technological University Dublin - City Campus, Grangegorman, Dublin, D07 H6K8, Ireland
2022en
ABI

Аннотация

The rising world population and its corresponding energy demands pose a considerable burden on natural energy sources. The exploitation of fossil fuels at such an alarming rate blurs the goals of sustainable development and controlling global warming as pledged during the Paris Agreement. Due to the detrimental effects of exhausts from conventional diesel fuel on the environment, biodiesel has earned significant importance during the last decade. Biodiesel is produced from different feedstocks such as neem oil, palm oil, waste frying oil, vegetable oil, animal fat, microbial oil, etc. These feedstocks react with acidic, alkaline, enzymic, homogeneous, heterogeneous, and hybrid Deep Eutectic Solvents (DES) catalysts, along with monohydric alcohol via transesterification reaction. The flexibility in its feedstock and the type of catalysts used, production cost, biodegradable and renewable nature makes it a promising alternative fuel than conventional diesel. The selection of apt feedstock and catalyst is the challenging task and governing factor of economic biodiesel production. Green solvents such as DES have high thermal stability and low volatility and can address the economic and green production issues significantly as compared to conventional alkali and acid catalysts. This review bridges the gap between the selection of feedstock and optimal catalyst for the respective feedstock. The exploration of DES fills the gap by attributing to 3Rs (i.e., recyclability, recovery, and reusability). This review highlights the contemporary trends and prospects in the selection of the feedstocks, synthesis routes, and catalysts for the transesterification reactions for biodiesel production.

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