Rheology and Thixotropy of Cement Pastes Containing Polyacrylamide

In this article, the rheological and thixotropic properties of fresh cement pastes (fcps) with nonionic polyacrylamide (PAM) are investigated through the coaxial rotary method. The B-HB model is resorted to fit the shear stress versus shear rate diagram, from which the slurry plastic viscosity is particularly discussed. The results show that with the development of PAM, the plastic viscosity increases first, then decreases, and then increases again, exhibiting the “up-down-up” trend, which is consistent with the fcps fluidity. The adsorption, lubrication, and entanglement mechanisms of PAM are successfully used to interpret this phenomenon. Combined with the suspension density, the relationship among plastic viscosity, flowability, and density is successfully established follower via a multivariate linear regression method. The Durbin-Watson coefficient, variance inflation factor, <a:math xmlns:a="http://www.w3.org/1998/Math/MathML" id="M1"> <a:mi>μ</a:mi> </a:math> significance, <c:math xmlns:c="http://www.w3.org/1998/Math/MathML" id="M2"> <c:mi>ρ</c:mi> </c:math> significance, and <e:math xmlns:e="http://www.w3.org/1998/Math/MathML" id="M3"> <e:msup> <e:mrow> <e:mi>R</e:mi> </e:mrow> <e:mrow> <e:mn>2</e:mn> </e:mrow> </e:msup> </e:math> are 2.122, 1.024, 0.014, 0.004, and 0.776, respectively, demonstrating the feasibility of fitting formula. Besides that, the PAM containing slurry which exhibits the explicit thixotropy is also found according to the appeared hysteresis curve during one shearing cycle. With the increase of PAM dosage, the thixotropic indexes including Th1 and Th2 decreased, until the PAM exceeded 0.5%-0.6% dosage, both of them yielded negative values. The phenomenon that the fcps final shear stress exceeds its initial value occurs.

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