Статья

Dimensionality Mediated Highly Repeatable and Fast Transformation of Coordination Polymer Single Crystals for All-Optical Data Processing

Nikita K. KulachenkovSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaMarina O. BarsukovaFunctional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center (AMPM), Division of Physical Sciences and Engineering (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi ArabiaPavel V. AlekseevskiySchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaAleksandr A. SapianikFunctional Materials Design, Discovery and Development Research Group (FMD3), Advanced Membranes and Porous Materials Center (AMPM), Division of Physical Sciences and Engineering (PSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi ArabiaMaxim SergeevSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaAndrei N. YankinSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaAndrei A. KrasilinIoffe Institute, St. Petersburg 194021, RussiaSemyon V. BachininSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaSergei A. ShipilovskikhDepartment of Chemistry, Perm State University, Perm, 614990, RussiaPetr PoturaevDepartment of Chemistry, Perm State University, Perm, 614990, RussiaН. А. МедведеваDepartment of Chemistry, Perm State University, Perm, 614990, RussiaЕ. С. ДенисламоваPerm National Research Polytechnic University, Perm 614990, RussiaP. S. ZelenovskiyInstitute of Natural Sciences and Mathematics, Ural Federal University, Yekaterinburg 620000, RussiaVladimir V. ShilovskikhSt. Petersburg State University, St. Petersburg 198504, RussiaYuliya KenzhebayevaSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaAnastasiia S. EfimovaSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaAlexander S. NovikovPeoples’ Friendship University of Russia (RUDN University), Moscow 117198, RussiaArtem LunevSchool of Physics and Engineering, ITMO University, St. Petersburg 197101, RussiaVladimir P. FedinNikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk 630090, RussiaValentin A. MilichkoInstitut Jean Lamour, Universit de Lorraine, UMR CNRS 7198, 54011 Nancy, France

2022en

ABI

Аннотация

A family of coordination polymers (CPs) based on dynamic structural elements are of great fundamental and commercial interest addressing modern problems in controlled molecular separation, catalysis, and even data processing. Herein, the endurance and fast structural dynamics of such materials at ambient conditions are still a fundamental challenge. Here, we report on the design of a series of Cu-based CPs [Cu(bImB)Cl2] and [Cu(bImB)2Cl2] with flexible ligand bImB (1,4-bis(imidazol-1-yl)butane) packed into one- and two-dimensional (1D, 2D) structures demonstrating dimensionality mediated flexibility and reversible structural transformations. Using the laser pulses as a fast source of activation energy, we initiate CP heating followed by anisotropic thermal expansion and 0.2–0.8% volume changes with the record transformation rates from 2220 to 1640 s–1 for 1D and 2D CPs, respectively. The endurance over 103 cycles of structural transformations, achieved for the CPs at ambient conditions, allows demonstrating optical fiber integrated all-optical data processing.

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Идентификаторы

DOI: 10.1021/acs.nanolett.2c01770

Цитирования и источники

Цитирований: 2Использованных источников: 0

Показатели — AkademScholar