A five-coordinate complex of copper chloride with 2-amino-5-ethyl-1,3,4-thiadiazole
Shakhnoza KadirovaUlugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700174, UzbekistanM. M. IshankhodzhaevaSt. Petersburg State Technological University of Plant Polymers, St. Petersburg, RussiaN.A. ParpievUlugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700174, UzbekistanЗ. КаримовTashkent Institute of Irrigation and Melioration, Tashkent, UzbekistanA.G. TozhiboevYunusov Institute of Chemistry of Plant Substances, Academy of Sciences of Uzbekistan Republic, Tashkent, UzbekistanB. TashkhodzhaevYunusov Institute of Chemistry of Plant Substances, Academy of Sciences of Uzbekistan Republic, Tashkent, Uzbekistan
ABI
Аннотация
A complex of Cu(II) chloride with 2-amino-5-ethyl-1,3,4-thiadiazole (AET) was prepared, and its structure was studied by IR spectroscopy and single crystal X-ray diffraction. The complex has the composition CuCl2(AET)4. The coordination sphere of the copper atom includes four molecules of the heterocyclic ligand coordinated via N atoms of thiadiazole rings and one of Cl− anions; the second Cl− anion is in the outer sphere.
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