Bis(2-amino-5-methyl-1,3,4-thiadiazole-κ<i>N</i> <sup>3</sup>)dichloridocobalt(II)
Song YeCollege of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, People's Republic of ChinaYufei JiCollege of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, People's Republic of ChinaMin-Yan KangCollege of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, People's Republic of ChinaZhiliang LiuCollege of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot, People's Republic of China
2012en
ABI
Аннотация
In the monomeric title complex, [CoCl(2)(C(3)H(5)N(3)S)(2)], the Co(II) atom is tetra-coordinated by two chloride anions and two N atoms from two monodentate 2-amino-5-methyl-1,3,4-thia-diazole ligands, giving a slightly distorted tetra-hedral stereochemistry [bond angle range about Co = 105.16 (12)-112.50 (10)°]. In the complex, the dihedral angle between the 1,3,4-thia-diazole planes in the two ligands is 72.8 (1)°. There are two intra-molecular N-H⋯Cl inter-actions in the complex unit, while in the crystal, inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonds link these units into a two-dimensional layered structure parallel to (011).
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