Thermal Decomposition of the Non-Interstitial Hydrides for the Storage and Production of Hydrogen
Wojciech GrochalaThe School of Chemistry, The University of Birmingham, Edgbaston, Birmingham, B15 2TT U.K., The Department of Chemistry, The University of Warsaw, Pasteur 1, 02093 Warsaw, Poland, and Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR U.KPeter P. EdwardsThe School of Chemistry, The University of Birmingham, Edgbaston, Birmingham, B15 2TT U.K., The Department of Chemistry, The University of Warsaw, Pasteur 1, 02093 Warsaw, Poland, and Inorganic Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QR U.K
2004en
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Аннотация
This review focuses on key aspects of the thermal decomposition of multinary or mixed hydride materials, with a particular emphasis on the rational control and chemical tuning of the strategically important thermal decomposition temperature of such hydrides, Tdec. An attempt is also made to predict the thermal stability of as-yet unknown, elusive or even unknown hydrides. The future of a particularly promising class of materials for hydrogen storage, namely the catalytically enhanced complex metal hydrides, is discussed. The predictions are supported by thermodynamics considerations, calculations derived from molecular orbital (MO) theory and backed up by simple chemical insights and intuition.
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