Influence of Titanium Dioxide (TiO2) Nanocrystallinity on the Optoelectrical Properties of Chitosan Biocomposite Films Prepared via Sol–Gel Casting

Bio-nanocomposite films were prepared using chitosan, gelatin, and varying concentrations (0, 0.5, 1.0, 2.0, and 5.0 wt%) of titanium dioxide (TiO2) nanoparticles in acetic acid via a casting method. The incorporation of TiO2 nanoparticles into the bio-chitosan matrix enhanced ultraviolet (UV) absorption and improved the films’ physical, mechanical, and electrical properties. Additionally, the TiO2-loaded films exhibited antimicrobial activity, contributing to the extended preservation of packaged products by inhibiting microbial growth. Notably, the bio-nanocomposite films containing 1.0 wt% TiO2 exhibited an electroactive response, bending under relatively low electric field strength (250 V/mm), whereas the control film without TiO2 required higher field strength (550 V/mm) to achieve bending. This indicates potential applications in electroactive actuators requiring precise movement control. Among the tested concentrations, films containing 0.5 wt% and 1.0 wt% TiO2 (Formulas 7 and 8) demonstrated optimal performance. These films presented a visually appealing appearance with no tear marks, low bulk density (0.91 ± 0.04 and 0.85 ± 0.18 g/cm3), a satisfactory electromechanical response at 250 V/m (17.85 ± 2.58 and 61.48 ± 6.97), low shrinkage percentages (59.95 ± 3.59 and 54.17 ± 9.28), high dielectric constant (1.80 ± 0.07 and 8.10 ± 0.73), and superior UV absorption compared with pure bio-chitosan films, without and with gelatin (Formulas 1 and 6).

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