Обзорная статья

The Role of Ligands in the Chemical Synthesis and Applications of Inorganic Nanoparticles

Amelie Heuer‐JungemannSchool of Physics and Astronomy, Faculty of Engineering and Physical Sciences, University of Southampton, Southampton SO17 1BJ, U.KNeus FeliuDepartment of Laboratory Medicine (LABMED), Karolinska Institutet, Stockholm 171 77, SwedenIoanna BakaimiSchool of Chemistry, Faculty of Engineering and Physical Sciences, University of Southampton, Southampton SO171BJ, U.KMajd A. HamalyKing Hussein Cancer Center, P. O. Box 1269, Al-Jubeiha, Amman 11941, JordanAlaaldin M. AlkilanyDepartment of Pharmaceutics & Pharmaceutical Technology, School of Pharmacy, The University of Jordan, Amman 11942, JordanIndranath ChakrabortyFachbereich Physik, CHyN, Universität Hamburg, 22607 Hamburg, GermanyAtif MasoodFachbereich Physik, Philipps Universität Marburg, 30357 Marburg, GermanyMaria Francesca CasulaDepartment of Mechanical, Chemical and Materials Engineering, University of Cagliari, Via Marengo 2, 09123 Cagliari, ItalyΑθανασία ΚωστοπούλουInstitute of Electronic Structure and Laser, Foundation for Research and Technology—Hellas, Heraklion, 71110 Crete, GreeceEunkeu OhKeyW Corporation, Hanover, Maryland 21076, United StatesKimihiro SusumuKeyW Corporation, Hanover, Maryland 21076, United StatesMichael H. StewartOptical Sciences Division, Code 5600, U.S. Naval Research Laboratory, Washington, D.C. 20375, United StatesIgor L. MedintzCenter for Bio/Molecular Science and Engineering, Code 6900, U.S. Naval Research Laboratory, Washington, D.C. 20375, United StatesEmmanuel StratakisInstitute of Electronic Structure and Laser, Foundation for Research and Technology—Hellas, Heraklion, 71110 Crete, GreeceWolfgang J. ParakFachbereich Physik, CHyN, Universität Hamburg, 22607 Hamburg, GermanyAntonios G. KanarasSchool of Physics and Astronomy, Faculty of Engineering and Physical Sciences, University of Southampton, Southampton SO17 1BJ, U.K

2019en

ABI

Аннотация

The design of nanoparticles is critical for their efficient use in many applications ranging from biomedicine to sensing and energy. While shape and size are responsible for the properties of the inorganic nanoparticle core, the choice of ligands is of utmost importance for the colloidal stability and function of the nanoparticles. Moreover, the selection of ligands employed in nanoparticle synthesis can determine their final size and shape. Ligands added after nanoparticle synthesis infer both new properties as well as provide enhanced colloidal stability. In this article, we provide a comprehensive review on the role of the ligands with respect to the nanoparticle morphology, stability, and function. We analyze the interaction of nanoparticle surface and ligands with different chemical groups, the types of bonding, the final dispersibility of ligand-coated nanoparticles in complex media, their reactivity, and their performance in biomedicine, photodetectors, photovoltaic devices, light-emitting devices, sensors, memory devices, thermoelectric applications, and catalysis.

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Идентификаторы

DOI: 10.1021/acs.chemrev.8b00733

Цитирования и источники

Цитирований: 2Использованных источников: 0

Показатели — AkademScholar