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Growing Carbon Nanotubes In Situ Surrounding Carbon Fiber Surface via Chemical Vapor Deposition to Reinforce Flexural Strength of Carbon Fiber Composites

Guangming YangSchool of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621010, ChinaFei ChengEngineering Research Center of Biomass Materials, Ministry of Education, Southwest University of Science and Technology, Mianyang 621010, ChinaShihao ZuoSchool of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621010, ChinaJinheng ZhangSchool of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621010, ChinaYang XuSchool of Materials and Chemistry, Southwest University of Science and Technology, Mianyang 621010, ChinaYunsen HuSchool of Mechanical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaXiaozhi HuDepartment of Mechanical Engineering, University of Western Australia, Perth, WA 6009, Australia
2023en
ABI

Аннотация

This study employed novel joint treatments to strengthen the carbon fiber reinforced polymer (CFRP) composites. Vertically aligned carbon nanotubes (VACNTs) were prepared in situ on the catalyst-treated CF surface via the chemical vapor deposition (CVD) method, intertwining into three-dimensional fiber-nets and fully surrounding CF to form an integrated structure. The resin pre-coating (RPC) technique was further used to guide diluted epoxy resin (without hardener) to flow into nanoscale and submicron spaces to eliminate void defects at the root of VACNTs. Three-point bending testing results showed the "growing CNTs and RPC"-treated CFRP composites yielded the best flexural strength, a 27.1% improvement over the specimens without treatment, while the failure modes indicated that the original delamination failure was changed into "flexural failure" with through-the-thickness crack propagation. In brief, growing VACNTs and RPC on the CF surface enabled toughening of the epoxy adhesive layer, reducing potential void defects and constructing the integrated quasi-Z-directional fiber bridging at the CF/epoxy interface for stronger CFRP composites. Therefore, the joint treatments of growing VACNTs in situ via the CVD method and RPC technique are very effective and have great potential in manufacturing high-strength CFRP composites for aerospace applications.

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