Ultrafine α-CoOOH Nanorods Activated with Iron for Exceptional Oxygen Evolution Reaction

Two-dimensional oxyhydroxide materials are proved to be a potential candidate for oxygen evolution reaction (OER). Robust, efficient, and cost-effective electrocatalysts are critical to overcome the sluggish kinetics and high overpotential of OERs. Herein, a simple co-precipitation method followed by solvothermal treatment is used to synthesize Fe-doped α-CoOOH at higher pH under optimum conditions for OER. The α-Fe0.24Co0.76OOH/NF illustrates superior OER electrocatalytic performance and requires an overpotential of only 280 mV to produce a current density of 50 mA cm–2 with excellent stability. The detailed analysis reveals that the exceptional OER performance originates from thin nanorods and partially due to the replacement of Fe in α-CoOOH. This work illustrates the presence of interlayer chloride ions through energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy.

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