Обзорная статья

Heterogeneous Trimetallic Nanoparticles as Catalysts

James W. M. CrawleyMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomIsla E. GowMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomNaomi LawesMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomIgor KowalecMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomLara KabalanMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomC. Richard A. CatlowDepartment of Chemistry, University College London, Gordon Street, London WC1H 0AJ, U.KAndrew J. LogsdailMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomStuart H. TaylorMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomNicholas F. DummerMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United KingdomGraham J. HutchingsMax Planck−Cardiff Centre on the Fundamentals of Heterogeneous Catalysis (FUNCAT), Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Main Building, Park Place, Cardiff CF10 3AT, United Kingdom

2022en

ABI

Аннотация

preparative conditions that are comparable to those applied for mono- and bimetallic nanoparticles. However, controlled elemental segregation and subsequent characterization remain challenging because of the heterogeneous nature of the systems. The multielement composition exhibits beneficial synergy for important oxidation, dehydrogenation, and hydrogenation reactions; in some cases, this is realized through higher selectivity, while activity improvements are also observed. However, challenges related to identifying and harnessing influential characteristics for maximum productivity remain. Computation provides support for the experimental endeavors, for example in electrocatalysis, and a clear need is identified for the marriage of simulation, with respect to both combinatorial element screening and optimal reaction design, to experiment in order to maximize productivity from this nascent field. Clear challenges remain with respect to identifying, making, and applying trimetallic catalysts efficiently, but the foundations are now visible, and the outlook is strong for this exciting chemical field.

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Идентификаторы

DOI: 10.1021/acs.chemrev.1c00493

Цитирования и источники

Цитирований: 2Использованных источников: 0

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