Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part II: new insights into the reaction of TPymT with Pb(NO<sub>3</sub>)<sub>2</sub>
Damir A. SafinDepartment of ChemistryKevin M. N. BurgessDepartment of ChemistryIlia KorobkovDepartment of ChemistryDavid L. BryceDepartment of ChemistryMuralee MurugesuDepartment of Chemistry
2014en
ABI
Аннотация
Reaction of TPymT with Pb(NO<sub>3</sub>)<sub>2</sub> in H<sub>2</sub>O leads to a mixture of two pseudopolymorphs, {[Pb<sub>2</sub>(TPymT)(H<sub>2</sub>O)(NO<sub>3</sub>)<sub>4</sub>]·H<sub>2</sub>O}<sub>n</sub>, <bold>1</bold> and [Pb<sub>2</sub>(TPymT)(NO<sub>3</sub>)<sub>4</sub>]<sub>n</sub>, <bold>2</bold>. Both pseudopolymorphs can be interconverted by dissolving in water upon heating and controlling the evaporation rate.
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