Crystal structure and Hirshfeld surface analysis of 8-azaniumylquinolinium tetrachloridozincate(II)
Gulnora Abdurakhmonovna UmirovaTermez State University, Barkamol avlod street 43, Termez city, UzbekistanKhayit TuraevTermez State University, Barkamol avlod street 43, Termez city, UzbekistanBekmurod Kh. AlimnazarovTermez State University, Barkamol avlod street 43, Termez city, UzbekistanSherzod KasimovTermez State University, Barkamol avlod street 43, Termez city, UzbekistanAbdulakhat DjalilovTashkent Scientific Research Institute of Chemical Technology, Township Shura-bazar, District of Zangiata, Tashkent 111116, UzbekistanБ. Т. ИбрагимовInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek Str. 83, Tashkent 700125, UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek Str. 83, Tashkent 700125, Uzbekistan
ABI
Аннотация
], which consists of a planar 8-aza-n-ium-yl-quinolinium dication and a tetra-hedral tetra-chloro-zincate dianion. The 8-amino-quinoline moiety is protonated at both the amino and the ring N atoms. In the crystal, the cations and anions are connected by inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds, forming sheets parallel to (001). Adjacent sheets are linked through π-π inter-actions involving the pyridine and arene rings of the 8-aza-niumylquinolinium dication. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯Cl (48.1%), H⋯H (19.9%), H⋯C/C⋯H (14.3%) (involving the cations) and H⋯Cl (82.6%) (involving the anions) interactions.
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