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Raman Spectroscopy as a Versatile Tool for Investigating Thermochemical Processing of Coal, Biomass, and Wastes: Recent Advances and Future Perspectives

Jun XuState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaQichen HeState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaZhe XiongState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaYun YuState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaShu ZhangJoint International Research Laboratory of Biomass Energy and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, ChinaXun HuSchool of Material Science and Engineering, University of Jinan, Jinan 250022, ChinaLong JiangState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaSheng SuState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaSong HuState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaYi WangState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, ChinaJun XiangState Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
2020en
ABI

Аннотация

Raman spectroscopy, as a rapid, high-precision, and nondestructive tool, can be used for analyzing the samples from gas to solid, from ex situ to in situ, from organic macromolecule to minerals. It has been demonstrated as a powerful tool for characterizing carbonaceous solid fuels and their thermal conversion products. This review provides a systematic overview of the application of Raman spectroscopy for investigating the entire thermochemical processing of coal, biomass, and wastes. After introducing the fundamentals of Raman spectroscopy, its application for characterizing the feedstock (raw coals, biomass, and wastes) is reviewed. Then, using the Raman spectroscopy for ex situ characterization of the products (char and ash) after reactions and in situ diagnostic during reactions are discussed. Besides, some potential advanced Raman spectroscopy techniques are further briefly introduced. Lastly, the challenges and prospects of using Raman spectroscopy to study thermochemical processes are discussed.

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