CO₂ Acceptor Gasification Process

The CO2 Acceptor Gasification Process is discussed in light of the required properties of the CaO acceptor. Equilibrium data for reactions involving the CO2 and sulfur acceptance and for sulfur rejection fit the process requirements. The kinetics of the reactions are also sufficiently rapid. Phase equilibrium data in the binary systems CaO—Ca(OH)2 and Ca(OH)2—CaCO3 show the presence of low melting eutectics, which establish operability limits for the process. Data were obtained in a continuous unit which duplicates process conditions which show adequate acceptor life. Physical strength of many acceptors is adequate, and life is limited by chemical deactivation. Contrary to earlier findings both limestones and dolomites are equally usable in the process. Melts in the Ca(OH)2—CaCO3 system are used to reactivate spent acceptors.

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