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On-site illicit-drug detection with an integrated near-infrared spectral sensor: A proof of concept

Ruben F. KranenburgDutch National Police, Unit Amsterdam, Forensic Laboratory, Kabelweg 25, Amsterdam, 1014 BA, the Netherlands; Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Postbus 94157, Amsterdam, 1090 GD, the Netherlands. Electronic address: [email protected]Fang OuMantiSpectra B.V, De Groene Loper 3, Eindhoven, 5612 AE, the Netherlands; Department of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsPetar ŠevoMaurangelo PetruzzellaMantiSpectra B.V, De Groene Loper 3, Eindhoven, 5612 AE, the Netherlands; Department of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsRenee de RidderAnne van KlinkenDepartment of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsKaylee D. HakkelDepartment of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsDon M. J. van ElstDepartment of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsRené van VeldhovenDepartment of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsFrancesco PaglianoMantiSpectra B.V, De Groene Loper 3, Eindhoven, 5612 AE, the Netherlands; Department of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the NetherlandsArian van AstenVan 't Hoff Institute for Molecular Sciences, University of Amsterdam, Postbus 94157, Amsterdam, 1090 GD, the Netherlands; Co van Ledden Hulsebosch Center (CLHC), Amsterdam Center for Forensic Science and Medicine, Postbus 94157, Amsterdam, 1090 GD, the NetherlandsAndrea FioreDepartment of Applied Physics and Eindhoven Hendrik Casimir Institute, Eindhoven University of Technology, PO Box 513, Eindhoven, 5600 MB, the Netherlands
2022en
ABI

Аннотация

Illicit-drug production, trafficking and seizures are on an all-time high. This consequently raises pressure on investigative authorities to provide rapid forensic results to assist law enforcement and legal processes in drug-related cases. Ideally, every police officer is equipped with a detector to reliably perform drug testing directly at the incident scene. Such a detector should preferably be small, portable, inexpensive and shock-resistant but should also provide sufficient selectivity to prevent erroneous identifications. This study explores the concept of on-site drugs-of-abuse detection using a 1.8 × 2.2 mm2 multipixel near-infrared (NIR) spectral sensor that potentially can be integrated into a smartphone. This integrated sensor, based on an InGaAs-on-silicon technology, exploits an array of resonant-cavity enhanced photodetectors without any moving parts. A 100% correct classification of 11 common illicit drugs, pharmaceuticals and adulterants was achieved by chemometric modelling of the response of 15 wavelength-specific pixels. The performance on actual forensic casework was investigated on 246 cocaine-suspected powders and 39 MDMA-suspected ecstasy tablets yielding an over 90% correct classification in both cases. These findings show that presumptive drug testing by miniaturized spectral sensors is a promising development ultimately paving the way for a fully integrated drug-sensor in mobile communication devices used by law enforcement.

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