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Metal-Organic Framework (MOF)/Epoxy Coatings: A Review

Farzad SeidiProvincial Key Lab of Pulp and Paper Science and Technology and Joint International Research Lab of Lignocellulosic Functional Materials, Nanjing Forestry University, Nanjing 210037, ChinaMaryam JouyandehCenter of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran 11155-4563, IranMohsen TaghizadehCenter of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran 11155-4563, IranAli TaghizadehCenter of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran 11155-4563, IranHenri VahabiUniversité de Lorraine, CentraleSupélec, LMOPS, F-57000 Metz, FranceSajjad HabibzadehDepartment of Chemical Engineering, Amirkabir University of Technology (Tehran Polytechnic), Tehran 15916-39675, IranKrzysztof FormelaDepartment of Polymer Technology, Faculty of Chemistry, Gdańsk University of Technology, Gabriela Narutowicza 11/12, 80-233 Gdańsk, PolandMohammad Reza SaebDepartment of Resin and Additives, Institute for Color Science and Technology, Tehran P.O. Box: 16765-654, Iran
2020en
ABI

Аннотация

Epoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coatings, e.g., adhesion to the substrate, anti-corrosion, mechanical, flame-retardant, and self-healing characteristics. Metal-organic frameworks (MOFs), a subclass of coordinative polymers with porous microstructures, have been widely synthesized in recent years and applied in gas and energy storage, separation, sensing, environmental science and technology, and medicine. Nevertheless, less attention has been paid to their performance in coatings. Well-known as micro- and nanoporous materials, with a tailorable structure consisting of metal ions and organic linkers, MOFs have a huge loading capacity, which is essential for the delivery of corrosion inhibitors. This review paper attempts to highlight the importance of epoxy/MOF composites for coating applications. A particular emphasis was explicitly placed on the anti-corrosion, flame-retardant, mechanical, and dielectric properties of epoxy/MOF coatings.

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