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Hyperthermal surface ionization of mercury from Pt(111)

Albert DanonSchool of Chemistry, Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv, IsraelAmichay VardiSchool of Chemistry, Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv, IsraelAviv AmiravSchool of Chemistry, Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv 69978, Tel Aviv, Israel
1990en
ABI

Аннотация

The Pt(111)-surface ionization of hyperthermal mercury atoms (4--10 eV) was studied in helium- and hydrogen-seeded supersonic molecular beams. In spite of the large energy difference of 4.7 eV between the atomic ionization potential and the surface work function, an efficient ionization was observed. The ionization mechanism is discussed in terms of an extensive energy transfer to the surface and the creation of a transient local hot spot. Analytical applications are mentioned.

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