Optical properties of high-T/sub c/ superconductors

The present status of optical spectroscopy of high-T/sub c/ superconductors is summarized. The optical properties of these materials resemble those of the more common transition metal oxides except for being highly anisotropic in the infrared (IR). This large IR anisotropy and a need to rely solely on reflectance techniques has hindered progress in obtaining accurate IR data and interpreting these data in terms of microscopic mechanisms. However, experimental consistency is now being approached with single-crystal samples, although interpretations of these data remain controversial and an unequivocal demonstration of a superconducting gap structure has not yet been achieved. The mid-IR exhibits an absorption band whose systematics are neither well established nor well understood. The situation in the visible-near-ultraviolet is better, partly because of greatly reduced optical anisotropy and the availability of alternative measurement techniques that are not strongly affected by the lower optical quality of sintered material. As polycrystalline, sintered samples can be prepared relatively easily over wide ranges of composition, doping, and chemical substitution, most work on studying the chemical systematics of these materials has been done in this spectral range and some of the structure that appears here has been positively identified.< <ETX xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">&gt;</ETX>

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