Статья

Synergistic stabilization of perovskite quantum dots via in situ encapsulation in a thiomethyl-functionalized covalent organic framework

Yuting XieScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaHongyan ZhangScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaPartha MaityCenter for Renewable Energy and Storage Technologies (CREST), Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi ArabiaJinchen QianScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaGaopeng XuScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaHao WangScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaTing ChenScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaKun ZhouScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaHanlin HuHoffmann Institute of Advanced Materials, Shenzhen Polytechnic, Shenzhen 518055, ChinaQingquan HeScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaJing LiScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaYongwu PengScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, ChinaOmar F. MohammedCenter for Renewable Energy and Storage Technologies (CREST), Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi ArabiaJun PanScience and Education Integration College of Energy and Carbon Neutralization, College of Materials Science and Engineering, Zhejiang Provincial Key Laboratory of Clean Energy Conversion and Utilization, Zhejiang University of Technology, Hangzhou 310014, China

2025en

ABI

Аннотация

Encapsulating perovskite nanocrystals within porous materials, particularly covalent organic frameworks (COFs), has emerged as a viable strategy for improving their resistance to water and light-induced degradation. However, previous studies have uncovered challenges arising from the intricate post-modification processes required for incorporating functional sites, which restricted the confinement growth of perovskite nanocrystals within COF pores. Herein, we synthesize a novel thiomethyl-functionalized COF (S-COF) by reacting 2,5-bis(3-(methylthio)propyloxy) terephthalate hydrazine (S-BMTH) with benzaldehyde,4,4′,4"-(1,3,5-triazine-2,4,6-triyl)tris- (TFPT). Subsequently, a highly stable composite, MAPbBr 3 @S-COF, is prepared by in situ growth of strongly confined MAPbBr 3 quantum dots (QDs) inside the S-COF pores. Interestingly, this composite demonstrates exceptional water stability for more than 1 year, attributed to the synergistic protection provided by the S-COF and Pb(OH)Br, which shield the QDs from degradation.

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Идентификаторы

DOI: 10.1016/j.xcrp.2024.102398

Цитирования и источники

Цитирований: 2Использованных источников: 0

Показатели — AkademScholar