Strong impact of light-induced conical intersections on the spectrum of diatomic molecules
Milan ŠindelkaSchulich Faculty of Chemistry, Department of Physics, and Minerva Center of Nonlinear Physics in Complex Systems, Technion?Israel Institute of Technology, Haifa 32000, IsraelNimrod MoiseyevSchulich Faculty of Chemistry, Department of Physics, and Minerva Center of Nonlinear Physics in Complex Systems, Technion?Israel Institute of Technology, Haifa 32000, IsraelLorenz S. CederbaumTheoretische Chemie, Physikalisch-Chemisches Institut Universität Heidelberg, D-69120 Heidelberg, Germany
2011en
ABI
Аннотация
We show that dressing of diatomic molecules by running laser waves gives rise to conical intersections (CIs). Due to presence of such CIs, the rovibronic molecular motions are strongly coupled. A pronounced impact of the CI on the spectrum of $Na_2$ molecule is demonstrated via numerical calculation for weak and moderate laser intensity, and an experiment is suggested on this basis. The position of the light induced CI and the strength of its non-adiabatic couplings can be chosen by changing the frequency and intensity of the used running laser wave. This offers new possibilities to control the photo-induced rovibronic molecular dynamics.
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