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Ammonia as a Carbon-Free Energy Carrier: NH<sub>3</sub> Cracking to H<sub>2</sub>

Elvira SpatolisanoGASP - Group on Advanced Separation Processes & GAS Processing, Dipartimento di Chimica, Materiali e Ingegneria Chimica “G. Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyLaura A. PellegriniGASP - Group on Advanced Separation Processes & GAS Processing, Dipartimento di Chimica, Materiali e Ingegneria Chimica “G. Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milano, ItalyAlberto R. de AngelisEni S.p.A. Research and Technological Innovation Department, via F. Maritano 26, 20097 San Donato Milanese, ItalySimone CattaneoEni S.p.A. Research and Technological Innovation Department, via F. Maritano 26, 20097 San Donato Milanese, ItalyErnesto RoccaroEni S.p.A. Research and Technological Innovation Department, via F. Maritano 26, 20097 San Donato Milanese, Italy
2023en
ABI

Аннотация

In the energy transition from fossil fuels to renewables,hydrogenis a realistic alternative to achieving the decarbonization target.However, its chemical and physical properties make its storage andtransport expensive. To ensure the cost-effective H-2 usageas an energy vector, other chemicals are getting attention as H-2 carriers. Among them, ammonia is the most promising candidate.The value chain of NH3 as a H-2 carrier, consideringthe long-distance ship transport, includes NH3 synthesisand storage at the loading terminal, NH3 storage at theunloading terminal, and its cracking to release H-2. NH3 synthesis and cracking are the cost drivers of the valuechain. Also, the NH3 cracking at large scale is not a maturetechnology, and a significant effort has to be made in intensifyingthe process as much as possible. In this respect, this work reviewsthe available technologies for NH3 cracking, criticallyanalyzing them in view of the scale up to the industrial level.

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