Study of the crystal field of a paramagnetic crystal by the uniaxial compression method
V. N. VasyukovDonetsk Physicotechnical Institute, Academy of Sciences of the Ukrainian SSRС. Н. ЛукинDonetsk Physicotechnical Institute, Academy of Sciences of the Ukrainian SSRG. A. TsintsadzeDonetsk Physicotechnical Institute, Academy of Sciences of the Ukrainian SSR
ABI
Аннотация
A study is made of the low-temperature features of the crystal field acting on a Ni2+ ion replacing a Zn2+ ion in a ZnSiF6·6H2O crystal. It is shown that the axial distortion of the water molecule complex forming the immediate environment of the paramagnetic ion is a compression along the third-order axis. The wide potentialities of the use of the method of axial pressures for perturbing the energy states of a paramagnetic ion are demonstrated.
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