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Effect of Heptadecane on Sorption of 2,6-di-Tert-butyl-4-Methylphenol by Polyethylene

Alexander Marina Institute of Chemical Physics, the USSR Academy of Sciences , 117334 , Moscow , USSRYu.A. Shlyapnikova Institute of Chemical Physics, the USSR Academy of Sciences , 117334 , Moscow , USSRA. Zh. Makhkamovb Polytechnical Institute , 700011 , Tashkent , USSRА.T. Dzhalilovb Polytechnical Institute , 700011 , Tashkent , USSR
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Abstract The sorption of vapors of 2,6-di-tert-butyl-4-methylphenol (DTP) by HDPE containing different concentrations of heptadecane has been studied using the ultraviolet spectrometry method. The isotherms of DTPh sorption at 100–200°C are presented by the Langmuir equation. The concentration of sorption of DTPh has no dependence on temperature, but depends on the concentration of heptadecane in a polymer. The heats of dissolution of DTPh in polyethylene have been determined. Key Words: Sorptionpolyethylene

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