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Third-harmonic generation in polyvinylpirrolidone-based metallic complexes

R. A. GaneevA. I. Ryasnyanskiı̆М. К. КодировSh. R. KamalovV. A. LiInstitute of Chemistry and Physics of Polymers, Academy of Sciences of Uzbekistan, Tashkent, 700128, UzbekistanR. I. TugushevT. Usmanov
Optics and Spectroscopyjournal2002en
ABI

Аннотация

The third-order nonlinear susceptibilities of the aqueous solutions of polyvinylpirrolidone doped with iron and zinc were studied by the method of third-harmonic generation with 1064-nm Nd:YAG laser radiation. The efficiencies of transformation into the third harmonic in these metallic complexes were 8×10−7 and 5×10−7, respectively. To determine the role of the Kerr effect in the transformation process, the nonlinear refractive index of the iron-doped polyvinylpirrolidone solution was measured by the Z-scan method and a value of n 2=−6.7×10−13 cgs unit was obtained.

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