The first report of a tetra-azide bound mononuclear cobalt(<scp>iii</scp>) complex and its comparative biomimetic catalytic activity with tri-azide bound cobalt(<scp>iii</scp>) compounds

Three new azide-bound cobalt(<sc>iii</sc>) complexes derived from three different triamines with extensive hydrogen bonded supramolecular chain structures and the role of their structural factors in oxidative coupling of <italic>o</italic>-aminophenols have been reported.

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