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Crystal structure and void analysis of tris(2-amino-1-methylbenzimidazolium) hexakis(nitrato-κ<sup>2</sup> <i>O</i>,<i>O</i>′)lanthanate(III)

Bakhtigul RuzievaNational University of Uzbekistan named after Mirzo Ulugbek, University street 4, Tashkent 100174, UzbekistanR.Zh. KunafievState Key Laboratory of Applied Organic Chemistry (SKLAOC), College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, People's Republic of ChinaZukhra C. KadirovaUzbekistan-Japan Innovation Center of Youth, University street 2B, Tashkent 100095, UzbekistanShahlo DaminovaNational University of Uzbekistan named after Mirzo Ulugbek, University street 4, Tashkent 100174, Uzbekistan
Acta Crystallographica Section E Crystallographic Communicationsjournal2022en
ABI

Аннотация

The organic–inorganic complex salt, (C 8 H 10 N 3 ) 3 [La(NO 3 ) 6 ], comprises a network of N-protonated 2-amino-1-methylbenzimidazolium cations and hexakis(nitrato)lanthanate(III) anions. The La III atom is twelve-coordinate within a distorted icosahedral environment. In the unit cell, each pair of the La III atoms lie nearly on one of the crystallographic glide planes. In the crystal structure, there are several N—H...O hydrogen-bonding interactions between the cations and terminal oxygen atoms from the nitrate moieties of the [La(NO 3 ) 6 ] 3– anion. Additional weak C—H...O hydrogen bonds between the cations and anions consolidate the three-dimensional arrangement of the structure. A packing analysis was performed to check the strength of the crystal packing.

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Мавзулар

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Organic Frameworks: Synthesis and Applications

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DOI
10.1107/s2056989022005163

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