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Semiconductor facet junctions for photocatalytic CO<sub>2</sub> reduction

Yisong FanThe Key Laboratory of Photonic Devices and Materials, Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences , Hefei , Anhui , P. R. ChinaChao ZhangHefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation, Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, University of Science and Technology of China , Hefei , Anhui 230026 , P. R. ChinaShavkat MamatkulovInstitute of Materials Science of Uzbekistan Academy of Sciences , Ch. Aytmatova street 2B , Tashkent 100084 , UzbekistanOlim RuzimuradovInstitute of Materials Science of Uzbekistan Academy of Sciences , Ch. Aytmatova street 2B , Tashkent 100084 , UzbekistanJingxiang LowHefei National Laboratory for Physical Sciences at the Microscale, Collaborative Innovation, Center of Chemistry for Energy Materials (iChEM), School of Chemistry and Materials Science, National Synchrotron Radiation Laboratory, University of Science and Technology of China , Hefei , Anhui 230026 , P. R. China
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Abstract Photocatalytic carbon dioxide (CO 2 ) conversion has been recognized as one of the promising strategies for unraveling current environmental and energy problems attributed to the growing fossil fuel consumption of the human society because it can directly harness incident sunlight energy for converting waste CO 2 into valuable compounds. Increasing attention has been provoked to the semiconductor facet junction photocatalysts due to their unique feature in enhancing the photogenerated electron–hole pair utilization toward improving the photocatalytic CO 2 conversion performance. In the past decade, significant breakthroughs in the semiconductor facet junction photocatalysts for photocatalytic CO 2 conversion. In this review, we give a brief introduction on the development and the idea of the semiconductor facet junction photocatalysts. Then, the unique advantages of the semiconductor facet junction photocatalysts for photocatalytic CO 2 conversion are summarized. Subsequently, the recent development of semiconductor facet junction photocatalysts in photocatalytic CO 2 conversion is overviewed. We end this review by presenting the perspectives and challenges in this field for its future advancement toward practical applications. This review is expected to push forward the development of not only photocatalytic CO 2 conversion but also other energy and environmental photocatalytic applications.

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