Мақола

Synthesis, structure and Hirshfeld surface analysis of diaquadinitratobis(4-nitroaniline)copper(II)

Sanjar Nayimovich KamolovNational University of Uzbekistan named after Mirzo Ulugbek, Tashkent, 100174, University str. 4., UzbekistanB. BabaevNational University of Uzbekistan named after Mirzo Ulugbek, Tashkent, 100174, University str. 4., UzbekistanAziz B. IbragimovInstitute of General and Inorganic Chemistry of Uzbekistan Academy of Sciences, Tashkent, 100125, M.Ulugbek Str., 77a, UzbekistanYuldash YakubovInstitute of General and Inorganic Chemistry of Uzbekistan Academy of Sciences, Tashkent, 100125, M.Ulugbek Str., 77a, UzbekistanAkhrorjon AbdullaevInstitute of General and Inorganic Chemistry of Uzbekistan Academy of Sciences, Tashkent, 100125, M.Ulugbek Str., 77a, UzbekistanБ. Т. ИбрагимовInstitute of Bioorganic Chemistry of Uzbekistan Academy of Sciences, Tashkent, 100140, M.Ulugbek Str., 83, UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry of Uzbekistan Academy of Sciences, Tashkent, 100140, M.Ulugbek Str., 83, Uzbekistan

Acta Crystallographica Section E Crystallographic Communicationsjournal2022en

ABI

Аннотация

A new metal complex, [Cu(NO 3 ) 2 (C 6 H 6 N 2 O 2 ) 2 (H 2 O) 2 ], was synthesized from water–ethanol solutions of Cu(NO 3 ) 2 and 4-nitroaniline (PNA). The complex molecules are located on inversion centers in monoclinic crystals with space group P 2 1 / c . The copper(II) ions are monodentately coordinated by two neutral PNA molecules through the nitrogen atom of the amino group, two NO 3 − anions and two water molecules. The coordination polyhedron of the central ion is a distorted octahedron as a result of the Jahn–Teller effect. There is a weak intramolecular hydrogen bond between the N—H group and the oxygen atom of one nitrate anion. Six relatively weak intermolecular hydrogen bonds associate the complex molecules into a three-dimensional network. The Hirshfeld surface analysis indicates that 55.8% of the intermolecular interactions are from O...H/H...O contacts, 13.3% are from H...H contacts while other contributions are from C...O/O...C, C...H/H...C, O...O and other contacts.

Ҳали таржима қилинмаган

Мавзулар

Crystal structures of chemical compounds Magnetism in coordination complexes Metal complexes synthesis and properties

Идентификаторлар

DOI: 10.1107/s2056989022010404

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