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Removal of Rhodamine B from Wastewater by Adsorption using Iron Oxide-Polymer Composite Material

Davron EshtursunovDepartment of Polymer Chemistry, Faculty of Chemistry, National University of Uzbekistan, Tashkent 100174, UzbekistanArofat InkhonovaDepartment of Polymer Chemistry, Faculty of Chemistry, National University of Uzbekistan, Tashkent 100174, UzbekistanSunnat BotirovDepartment of Polymer Chemistry, Faculty of Chemistry, National University of Uzbekistan, Tashkent 100174, UzbekistanYusuf Fayzullayevhttps://orcid.org/0009-0006-5929-6469Bekchanov DavronbekDepartment of Polymer Chemistry, Faculty of Chemistry, National University of Uzbekistan, Tashkent 100174, UzbekistanMukhtarjan MukhamedievDepartment of Polymer Chemistry, Faculty of Chemistry, National University of Uzbekistan, Tashkent 100174, Uzbekistan
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Аннотация

The discharge of dye-containing wastewater from textile, paper and plastic industries poses serious environmental pollution hazards. This study investigates the potential application of an ion exchange material-iron oxide composite to remove rhodamine B dye from aqueous solutions. The composite was synthesized by incorporating iron oxide nanoparticles into a cationic ion exchange matrix containing amine groups with high affinity for rhodamine B dye. Batch adsorption experiments were conducted under controlled pH, temperature and initial rhodamine B dye concentrations. The results demonstrate that the composite material can effectively remove rhodamine B dye, with adsorption capacities reaching 23570.4 mg/g and removal efficiencies over 90% under the optimal conditions at pH 7 and 30 ºC. The adsorption followed pseudo-second order kinetics indicating chemisorption as the main mechanism. The findings suggested that this composite material can serve as an efficient and low-cost adsorbent for removing cationic dyes like rhodamine B dye from textile and other industrial wastewaters due to its high capacity, rapid adsorption rate and magnetic properties that enable easy separation.

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