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Interactions of Ionic Liquids With Metal Surface: Effect of Cations And Anions

Omar DagdagCentre for Materials Science, College of Science, Engineering and Technology, University of South Africa, Johannesburg 1710, South AfricaRajesh HaldharSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaSeong‐Cheol KimSchool of Chemical Engineering, Yeungnam University, Gyeongsan 38541, Republic of KoreaElyor BerdimurodovFaculty of Chemistry, National University of Uzbekistan, Tashkent, 100034, UzbekistanChandrabhan VermaCenter of Research Excellence in Corrosion, Research Institute, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi ArabiaEkemini D. AkpanCentre for Materials Science, College of Science, Engineering and Technology, University of South Africa, Johannesburg 1710, South AfricaEno E. EbensoCentre for Materials Science, College of Science, Engineering and Technology, University of South Africa, Johannesburg 1710, South Africa

BENTHAM SCIENCE PUBLISHERS eBooksebook platform2023en

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Аннотация

The motivation behind recreating this chapter is to give a summary of the bibliographical insights expected to make the segment. In the first part, we examine the adsorption of ionic liquids (ILs) as efficient, effective and eco-friendly corrosion inhibitors for various alloys and metals surface in different corrosive media environments and the restraint and coordination chemistry of ionic liquids. The anticorrosive activity of different ILs has been examined with electrochemical techniques followed by weight-loss measurement. The impact of the ILs composition (polar and nonpolar substituents in anions &amp; cations, and alkyl tail length), temperature, concentration, and nature of the medium, which influence the metal corrosion protection, was discussed. In the second part, we examine the interfacial structure and adsorption mechanism of different ILs on the Au (111) surface investigated via quantum chemical calculations.

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Мавзулар

Ionic liquids properties and applications Corrosion Behavior and Inhibition Electrochemical Analysis and Applications

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DOI: 10.2174/9789815136234123010010

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