Мақола

Crystal structure and Hirshfeld surface analysis of bis(benzoylacetonato)(ethanol)dioxidouranium(VI)

Xolida JabborovaInstitute of General and Inorganic Chemistry, Academy of Sciences of Uzbekistan, 100170, M. Ulugbek Str 77a, Tashkent, UzbekistanXusnida TursinboyevaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 UzbekistanBakhtigul RuzievaAlfraganus University, 100190, Uzbekistan, Tashkent, Yunusabad district, Yukori Karakamish Street 2, UzbekistanK. K. TurgunovS. Yunusov Institute of the Chemistry of Plant Substances Academy of Sciences of Uzbekistan Mirzo Ulugbek Str 77 Tashkent 100170 UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, 100125, M. Ulugbek Str. 83, Tashkent, UzbekistanAkmaljon TojiboevNamangan State University, Boburshoh str. 161, Namangan, 160107, UzbekistanShahlo DaminovaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 Uzbekistan

Acta Crystallographica Section E Crystallographic Communicationsjournal2024en

ABI

Аннотация

A new uranium metal–organic complex salt, [U(C 10 H 9 O 2 ) 2 O 2 (C 2 H 6 O)], with benzoyl acetone, namely, bis(benzoylacetonato)(ethanol)dioxidouranium(VI), was synthesized. The compound has monoclinic P 2 1 / n symmetry. The geometry of the seven-coordinate U atom is pentagonal bipyramidal, with the uranyl oxygen atoms in apical positions. In the complex, the ligands bind to the metal through oxygen atoms. Additional weak O—H...O contacts between the cations and anions consolidate the three-dimensional arrangement of the structure. On the Hirshfeld surface, the largest contributions come from the short contacts such as van der Waals forces, including H...H, O...H and C...H. Interactions including C...C and O...C contacts were also observed; however, their contribution to the overall cohesion of the crystal structure is minor. A packing analysis was performed to check the strength of the crystal packing.

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Мавзулар

Crystal structures of chemical compounds Lanthanide and Transition Metal Complexes Crystallography and molecular interactions

Идентификаторлар

DOI: 10.1107/s2056989024010417

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