Мақола

SYNTHESIS, STRUCTURE AND HIRSHFELD SURFACE ANALYSIS OF THE COMPLEX COMPOUND BASED ON Cd(II) SALT AND O-PHENYLENEDIAMINE

Ashur AkhatovFaculty of Chemistry, Termez State University, Termez, UzbekistanKhayit TuraevFaculty of Chemistry, Termez State University, Termez, UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Tashkent, UzbekistanIbragim UmbarovFaculty of Chemistry, Termez State University, Termez, UzbekistanXurshidjon TillaevFaculty of Chemistry, Termez State University, Termez, UzbekistanAbror NomozovDepartment of Chemical Engineering, Termez State University of Engineering and Agrotechnologies. Termez, UzbekistanNuriddin UralovFaculty of Chemistry, Termez State University, Termez, UzbekistanErkin Alim oglu EshdavlatovFaculty of Chemistry, Termez State University, Termez, Uzbekistan

Recent Contributions to Physicsjournal2024en

ABI

Аннотация

In this paper studying the synthesis, crystal structure and Hirschfeld surfaceanalysis of a new complex compound containing [Cd(OPD)3SO4]·H2O obtained based on o-phenylenediamine (OPD) are given. The molecular and crystal structure of this complex compound was determined using the RTT method. In the inner sphere of the complex, twomolecules of OPD in the chelate state and one molecule of OPD in the monodentate state are attached to the central atom. The complex compound forms a distorted octahedral shape in space. [Cd(OPD)3SO4]·H2O complex compound syngonia is monoclinic, space group P21/c and crystal parameters are a=22.5631(5)Å, b=8.1292(2) Å, c=11.6094(4) Å. In the crystal structure of the complex, 5Cd−N (2.350(5) Å−2.448(5)Å) and 1 Cd−O (2.355(5) Å) bonds form an inner sphere. The crystal structure of the molecule is formed by intra-and intermolecular hydrogen bonds of the type N---H...O and O---C...O. In the Hirschfeld surface analysis of [Cd(OPD)3SO4]·H2O complex compound, the main interactions are H...H (54.4%), O...H/H...O (26.7%) and H...C/C...H (16.7%) organizes.

Ҳали таржима қилинмаган

Мавзулар

Dendrimers and Hyperbranched Polymers Nonlinear Optical Materials Research Metal-Organic Frameworks: Synthesis and Applications

Идентификаторлар

DOI: 10.26577/rcph.2024.v91.i4.a8

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