Synthesis, crystal structure and Hirshfeld surface analysis of (2-amino-1-methylbenzimidazole-κ<i>N</i> <sup>3</sup>)aquabis(4-oxopent-2-en-2-olato-κ<sup>2</sup> <i>O</i>,<i>O</i>′)nickel(II) ethanol monosolvate
Kyzlarkhan SiddikovaKarshi Engineering Economics Institute, Mustakillik Avenue, 225, Karshi 180100, UzbekistanMurodov SardorNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 UzbekistanAkmaljon TojiboyevZukhra C. KadirovaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 UzbekistanJamshid AshurovInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, Mirzo, Ulugbek Street 83, Tashkent 100125, UzbekistanShahlo DaminovaNational University of Uzbekistan named after Mirzo Ulugbek University Street 4 Tashkent 100174 Uzbekistan
ABI
Аннотация
The molecule of the title compound, [Ni(C 5 H 7 O 2 ) 2 (C 8 H 9 N 3 )(H 2 O)]·C 2 H 5 OH, has triclinic ( P \overline{1}) symmetry. This compound is of interest for its antimicrobial properties. The asymmetric unit comprises two independent complex molecules, which are linked by N—H...O and O—H...O hydrogen bonds along [111]. Hirshfeld surface analysis indicates that 71.7% of intermolecular interactions come from H...H contacts, 17.7% from C...H/H...C contacts and 7.6% from O...H/H...O contacts, with the remaining contribution coming from N...H/H...N, C...N/N...C, C...C and O...O contacts.
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