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Investigating Performance Properties of Three New Types of <scp>UF</scp> Membranes for Carwash Sector Applications

Eman S. A. Al‐SammarraieEnvironmental Research Center University of Technology‐Iraq Baghdad IraqB. S. M. Al-GheziInstitute of Chemical Technology Ural Federal University Named After First President of Russia B. N. Yeltsin Yekaterinburg RussiaWahab K. A. Al‐IthawiEnergy and Renewable Energies Technology Center University of Technology‐Iraq Baghdad IraqIgor L. NikonovInstitute of Chemical Technology Ural Federal University Named After First President of Russia B. N. Yeltsin Yekaterinburg RussiaIgor S. КоvalevInstitute of Chemical Technology Ural Federal University Named After First President of Russia B. N. Yeltsin Yekaterinburg RussiaAqeel M.K. AltobeeInstitute of Chemical Technology Ural Federal University Named After First President of Russia B. N. Yeltsin Yekaterinburg RussiaТ. М. СабироваInstitute of Chemical Technology Ural Federal University Named After First President of Russia B. N. Yeltsin Yekaterinburg RussiaGrigory V. ZyryanovInstitute of Chemical Technology Ural Federal University Named After First President of Russia B. N. Yeltsin Yekaterinburg RussiaMohammed AwadDepartment of Chemical Engineering Toronto Metropolitan University Toronto Ontario CanadaHicham MeskherDivision of Process Engineering, College of Science and Technology Chadli Bendjedid University Eltarf AlgeriaQusay F. AlsalhyMembrane Technology Research Unit, Department of Chemical Engineering University of Technology‐Iraq Baghdad Iraq
ABI

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ABSTRACT Carwash facilities generate considerable amounts of wastewater, which presents both an environmental challenge and a potential alternative water source. To facilitate reuse, this wastewater must meet stringent quality standards. In this study, three novel ultrafiltration (UF) membranes were developed for the first time to treat carwash wastewater (CWW). These membranes were fabricated from postmodified (PM) polyvinyl chloride (PVC) derivatives: PVC modified with 4‐tert‐octylthiophenol (PP1), 4‐tert‐butylthiophenol (PP2), and thiophenol (PP3) using a mechanosynthesis approach. The membranes were synthesized by incorporating the respective modified polymers into a solvent mixture of tetrahydrofuran (THF) and N‐methyl‐2‐pyrrolidone (NMP) via the casting solution technique. Structural characterization was performed using Fourier‐transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The membranes exhibited thicknesses of 143 μm (PP1), 178 μm (PP2), and 139 μm (PP3), porosity ranging from 64.67% to 73.33%, and average pore sizes between 23.41 and 28.81 nm. Performance testing revealed that PP1 demonstrated the highest rejection rates for suspended solids (99%), oil products (82.4%), and surfactants (79%), with a flux of 40.24 L/m 2 h. Although PP3 achieved the highest water flux (61.82 L/m 2 h), its rejection performance was slightly lower. Retentate underwent biological treatment, removing 85%–90% of organic matter, supporting sustainable wastewater reuse.

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