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Synthesis And Evaluation Of Metal-Doped Rice Husk Silica For Iodine Vapor Capture

Niyazova Dilnoza BakhtiyorovnaResearcher (PhD) , Institute of General and Inorganic Chemistry , ASc RUz , Tashkent , UzbekistanMamajonov Bakhodirjon MadaminovichNamangan Institute of Engineering and Technology , Namangan , Uzbekistan Doctoral student (DSc) ,Khoshimov Shakhrom MansurovichAbdikamalova Aziza BakhtiyarovnaInstitute of General and Inorganic Chemistry , ASc RUz , Doctor of Chemical Sciences , Professor , Uzbekistan Chief researcher ,Eshmetov Izzat DusimbatovichMamataliev Nozim NimadjonovichInstitute of General and Inorganic Chemistry , ASc RUz , Doctor of Chemical Sciences , UzbekistanAlisher Maksetbaevich KalbaevJunior Researcher , PhD , Institute of General and Inorganic Chemistry , ASc RUz , Tashkent , Republic of Uzbekistan , Uzbekistan
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Аннотация

Amorphous silica was synthesized from rice husk and doped with Ag, Cu, Zn, or Bi to develop iodine sorbents. The resulting metal-loaded silica materials, produced via thermal treatment after wet impregnation, were tested for iodine vapor uptake at 25 °C for 1 hour. Bismuth- and copper-modified silica achieved the highest capacities (0.5–0.6 g I2/g), outperforming silver (0.2 g/g) and zinc (0.15 g/g). The enhanced performance stems from chemisorption via metal iodide formation (AgI, CuI, ZnI2, BiI3). These results align with literature values and demonstrate a sustainable route to efficient iodine capture using low-cost rice husk silica combined with targeted metal additives.

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