Finely tuning MOFs towards high performance in C<sub>2</sub>H<sub>2</sub> storage: synthesis and properties of a new MOF-505 analogue with an inserted amide functional group
Mingxing ZhangCollaborative Innovation Center of Advanced MicrostructuresBin LiDepartment of ChemistryYunzhi LiChinaQian WangCollaborative Innovation Center of Advanced MicrostructuresWenwei ZhangCollaborative Innovation Center of Advanced MicrostructuresBanglin ChenDepartment of ChemistryShuhua LiChinaYi PanCollaborative Innovation Center of Advanced MicrostructuresXiao‐Zeng YouCollaborative Innovation Center of Advanced MicrostructuresJunfeng BaiCollaborative Innovation Center of Advanced Microstructures
2016en
ABI
Аннотация
Aiming to improve the acetylene (C2H2) storage capability of MOFs, we successfully designed NJU-Bai 17, a new analogue of MOF-505 with an inserted amide functional group which exhibits almost record high C2H2 uptakes of 222.4 cm(3) g(-1) at 296 K and 296 cm(3) g(-1) at 273 K under 1 bar. This result has been further supported by the determination of the heat of C2H2 adsorption and Grand Canonical Monte Carlo (GCMC) and first-principle calculations.
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