Chemically complex double solid solution MAX phase-based ceramics in the (Ti,Zr,Hf,V,Nb)-(Al,Sn)-C system
Аннотация
Chemically complex MAX phase-based ceramics in the (Ti,Zr,Hf,V,Nb)-(Al,Sn)-C system were synthesised by reactive hot pressing for 30 min at 1250-1450C under a load of 30 MPa for the first time in this work. The dense bulk ceramics contained chemically complex double solid solution MAX phases, each comprising five M-elements and two A-elements. The predominant 211 (Ti 0.23 ,Zr 0.18 ,Hf 0.20 ,V 0.11 ,Nb 0.28 ) 2 (Al 0.42 ,Sn 0.58 )C MAX phase characterised all ceramics, while the 312 (Ti 0.23 ,Zr 0.31 ,Hf 0.31 ,V 0.08 ,Nb 0.08 ) 3 (Al 0.36 ,Sn 0.64 )C 2 and 211 (Ti 0.26 ,Zr 0.07 ,Hf 0.07 ,V 0.47 ,Nb 0.13 ) 2 (Al 0.66 , Sn 0.34 )C MAX phases were only present in the ceramics sintered at 1350-1450C. A limited amount (4-5 vol%) of parasitic phases (mainly, binary intermetallics) was found in the pseudo-binary carbidefree ceramics sintered at 1350-1450C.
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