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Emerging rechargeable aqueous aluminum ion battery: Status, challenges, and outlooks

Du YuanEnergy Research Institute, Nanyang Technological University, 637553, SingaporeJin ZhaoSchool of Materials Science and Engineering, Nanyang Technological University, 639798, SingaporeWilliam ManalastasSchool of Materials Science and Engineering, Nanyang Technological University, 639798, SingaporeSonal KumarSchool of Materials Science and Engineering, Nanyang Technological University, 639798, SingaporeMadhavi SrinivasanEnergy Research Institute, Nanyang Technological University, 637553, Singapore
2019en
ABI

Аннотация

Aluminum ion battery (AIB) technology is an exciting alternative for post-lithium energy storage. AIBs based on ionic liquids have enabled advances in both cathode material development and fundamental understanding on mechanisms. Recently, unlocking chemistry in rechargeable aqueous aluminum ion battery (AAIB) provides impressive prospects in terms of kinetics, cost, safety considerations, and ease of operation. To review the progress on AAIB, we discuss the critical issues on aluminum electrochemistry in aqueous system, cathode material design to overcome the drawbacks by multivalent aluminum ions, and challenges on electrolyte design, aluminum stripping/plating, solid-electrolyte interface (SEI) formation, and design of cathode materials. This review aims to stimulate exploration of high-performance AAIB and rationalize feasibility grounded on underlying reaction mechanisms.

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