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Incoherent interplane conductivity of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>κ</mml:mi><mml:mo>−</mml:mo><mml:mo>(</mml:mo><mml:mi mathvariant="normal">BEDT</mml:mi><mml:mo>−</mml:mo><mml:mi mathvariant="normal">TTF</mml:mi><mml:mrow><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">Cu</mml:mi><mml:mo>[</mml:mo><mml:mi mathvariant="normal">N</mml:mi><mml:mo>(</mml:mo><mml:mi mathvariant="normal">CN</mml:mi><mml:mo>)</mml:mo><mml:mn/></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mi mathvariant="normal">Br</mml:mi></mml:math>

J. J. McGuireDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1T. RõõmDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1A. V. ProninDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1T. TimuskDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1John A. SchlueterDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1M.E. KellyDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1A. M. KiniDepartment of Physics and Astronomy, McMaster University, Hamilton, Ontario, Canada L8S 4M1
2001lv
ABI

Аннотация

The interplane optical spectrum of the organic superconductor $\ensuremath{\kappa}\ensuremath{-}(\mathrm{B}\mathrm{E}\mathrm{D}\mathrm{T}\ensuremath{-}\mathrm{T}\mathrm{T}\mathrm{F}{)}_{2}\mathrm{Cu}[\mathrm{N}(\mathrm{CN}{)}_{2}]\mathrm{Br}$ was investigated in the frequency range from 40 to $40000 {\mathrm{cm}}^{\ensuremath{-}1}.$ The optical conductivity was obtained by Kramers-Kronig analysis of the reflectance. The absence of a Drude peak at low frequency is consistent with incoherent conductivity but in apparent contradiction to the metallic temperature dependence of the dc resistivity. We set an upper limit to the interplane transfer integral of ${t}_{b}^{2}{/t}_{\mathrm{ac}}\ensuremath{\approx}{10}^{\ensuremath{-}7}$ eV. A model of defect-assisted interplane transport can account for this discrepancy. We also assign the phonon lines in the conductivity to the asymmetric modes of the BEDT-TTF molecule.

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