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Synthesis, structure and magnetism of a new ferromagnetic hexanuclear nickel cluster with a dicubane-like core

S. WorlAnorganisch-Chemisches Institut, Im Neuenheimer Feld 270, D-69120 Heidelberg, GermanyHans PritzkowAnorganisch-Chemisches Institut, Im Neuenheimer Feld 270, D-69120 Heidelberg, GermanyIgor O. FritskyDepartment of Chemistry, National Taras Shevchenko University, 01033 Kiev, UkraineRoland KrämerAnorganisch-Chemisches Institut, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany
2004en
ABI

Аннотация

A new ferromagnetic nickel(II) hexameric structure based on the versatile N,O3-ligand 2,2',2"-nitrilotribenzoic acid has been prepared and characterised by X-ray crystallography and magnetic measurements; the compound represents a rare example of a nickel cluster with a dicubane-like core having only oxygen bridges.

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