Electrochemical glycosylation in the presence of a catalytic chemical mediator
Ludovic DrouinDepartment of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UKRichard G. ComptonDepartment of Chemistry, Physical and Theoretical Chemistry Laboratory, University of Oxford, UKAntony J. FairbanksDepartment of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UK
2008en
ABI
Аннотация
Abstract Electrochemical glycosylation of thioglycoside donors proceeds efficiently in an undivided cell in the presence of a catalytic amount of the chemical mediator (4‐bromophenyl) ammoniumyl hexachloroantimonate (BAHA). In comparison with electrochemical glycosylation alone, the use of a catalytic amount of BAHA greatly increases the rate of reaction, reduces the potential required and inhibits ester‐protecting group migrations. Copyright © 2008 John Wiley & Sons, Ltd.
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