Мақола

Chemical Glycosylation by Single Electron Transfer

Toshiki NokamiDepartment of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, 4-101 Koyamachominami, Tottori City 680-8552, Tottori (Japan),Toshiyuki ItohDepartment of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, 4-101 Koyamachominami, Tottori City 680-8552, Tottori (Japan),Kwok‐Kong Tony MongDepartment of Applied Chemistry, National Chiao Tung University, 1001, Ta-Hsueh Road, Hsinchu 300, Taiwan (ROC),

2015en

ABI

Аннотация

Abstract Oligosaccharides play important roles in nature; however, chemical synthesis of oligosaccharides is still difficult and not carried out in a fully automated manner. Among various methods, the activation of glycosyl donors by single electron transfer using electrochemical and photochemical methods has several benefits. In particular, electrochemical oxidation is a powerful method to activate glycosyl donors, including thioglycosides, which are one of the most popular class of glycosyl donors in modern chemical glycosylations. This review article covers the pioneering works of electrochemical glycosylations, other chemical glycosylations achieved by single electron transfer, and our recent approach to the automated solution‐phase synthesis of oligosaccharides based on the electrochemical method.

Ҳали таржима қилинмаган

Идентификаторлар

DOI: 10.1002/ijch.201400144

Иқтибослар ва манбалар

2 та иқтибос0 та фойдаланилган манба

Кўрсаткичлар — AkademScholar