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3,7-Bis(dimethylamino)phenothiazin-5-ium nitrate dihydrate

Savaridasson Jose KavithaDepartment of Chemistry, Bharathidasan University, Tiruchirappalli 24, IndiaM.M. RajDepartment of Chemistry, Bharathidasan University, Tiruchirappalli 24, IndiaKrishnaswamy PanchanatheswaranDepartment of Chemistry, Bharathidasan University, Tiruchirappalli 24, IndiaD.E. LynchSchool of Science and the Environment, Coventry University, Coventry CV1 5FB, England
2004en
ABI

Аннотация

The reaction of 3,7-bis­(di­methyl­amino)­pheno­thia­zin-5-ium chloride pentahydrate (methyl­ene blue) with silver nitrate in a 1:2 molar ratio in water yielded the title compound, C16H18N3S+·NO3−·2H2O, as one of the products. The cationic dye mol­ecules are planar and stacked in an antiparallel fashion, exhibiting π–π associations at a distance of 3.7040 (18) Å. The nitrate anion and the two water mol­ecules are involved in a hydrogen-bonding network that also includes the pheno­thia­zinium N atom.

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