Torsional vibrations of H<sub>2</sub>O molecules in crystalline Li<sub>2</sub>SO<sub>4</sub>·H<sub>2</sub>O
J.M. JanikInstitute of Chemistry of the Jagiellonian University, CracowJ.A. JanikInstitute of Nuclear Physics, CracowG. PytaszInstitute of Chemistry of the Jagiellonian University, CracowT. WasiutyńskiInstitute of Physics of the Jagiellonian University, Cracow
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Abstract Results of IR and Raman measurements for Li 2 SO 4 ·H 2 O and Li 2 SO 4 ·D 2 O are reported and compared with neutron inelastic scattering data. Bands at about 320,580, and 850 cm −1 are interpreted as connected with H 2 O torsions. A group theory analysis of the torsional vibrations of H 2 O molecules in the crystal is given.
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