Kinetics of Chemical Reactions of Stressed Polymers
А. А. ПоповInstitute of Chemical Physics, USSR Academy of SciencesГ. Е. Заиков
Institute of Chemical Physics, USSR Academy of SciencesN. N. SemeriovInstitute of Chemical Physics, USSR Academy of Sciences
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Abstract The effect of stress on the rate of chemical reactions is reviewed. It is shown that the sensitivity of the reaction rate to stress depends primarily on two factors; 1) the degree of change in the reactive site geometry, and 2) the energy content of the structural fragment affected by the reaction. Key Words: Stressed polymersreaction ratesozonationpolyolefins
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