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Model of high-T c superconductivity in low-coordination semiconductors and polymers

B. P. PopovPhysicotechnical InstituteK. D. TséndinA. F. Ioffe Physicotechnical Institute, Russian Academy of Sciences, St. Petersburg State Technical University, St. Petersburg
Technical Physics Lettersjournal1998en

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We propose a model in which the state with anomalously high conductivity observed in some lowcoordinated semiconductors and polymers when the temperature of the surrounding medium is T 0≈300 K, is described by the theory of the superconducting properties of a system of localized electron pairs. The superconducting properties of the model are determined by transport along a bipolaron band formed by localized pairs of carriers belonging to U − centers, i.e., intrinsic defects with a negative effective correlation energy

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