Asosiy kontentga oʻtish
AkademIndex

Xizmatlar

Maqola

Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)<sub>3</sub>][Cu(H<sub>-1</sub>pap)]<sub>2</sub>(NO<sub>3</sub>) · 8 H<sub>2</sub>O Featuring Octahedral Cationic and Square-planar Anionic Modules

Igor O. FritskyDepartment of Chemistry, Shevchenko University, 01033 Kiev, UkraineJ. Świątek-KozłowskaDepartment of Basic Medical Sciences, Medical University of Wroclaw, Wroclaw, PolandA. A. KapshukDepartment of Chemistry, Shevchenko University, 01033 Kiev, UkraineHenryk KozłowskiFaculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, Poland d Department of Chemistry, Karakalpak University, la Universitetskaya Str., Nukus 742000, UzbekistanT.Yu. SlivaDepartment of Chemistry, Shevchenko University, 01033 Kiev, UkraineElżbieta Gumienna‐KonteckaFaculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, PolandElena V. PrisyazhnayaDepartment of Chemistry, Shevchenko University, 01033 Kiev, UkraineTurganbay S. IskenderovDepartment of Chemistry, Karakalpak University, la Universitetskaya Str., Nukus 742000, Uzbekistan
Zeitschrift für Naturforschung Bjournal2000en

Ochiq kirish: yoʻq

ABI

Annotatsiya

Abstract The new mixed metal assembly [Ni(phen) 3 ][Cu(H -1 pap)] 2 (NO 3 ) · 8 H 2 O (2) (H 2 pap = CH 3 - C(=NO H)-C(O )-NH-(CH 2 ) 3 -NH-C(O )-C(=NOH)-CH 3 ) was obtained by co-crystallisation of [Li(H 2 O)4][Cu(H -1 pap)] · 2 H 2 O (1) and tris(1,10-phenanthroline)nickel(II) nitrate and studied by means of X-ray crystallography (triclinic, space group P1, a = 13.471(3), b = 13.641(3), c = 15.401(3) Å, α = 108.21(3), β = 97.73(3), γ = 107.74(3)°, V = 2476.6(9) Å , Z = 2 ,R1 = 0.0677 for 4672 unique reflections with I &gt; 2σ(I)). The assembly indicates a network structure and consists of isolated cationic and anionic modules (octahedral [Ni(phen) 3 ] 2+ and square-planar [Cu(H -1 pap)] - ), non-coordinated nitrate anions and solvating water molecules. The elements of the crystal structure are linked by interactions of different types: by an extended system of H bonds, stacking interactions between aromatic rings, long apical Cu-N contacts and specific π-π interaction between a deprotonated oxime group of the complex anion and a phenanthroline ligand

Hali tarjima qilinmagan

Mavzular

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Identifikatorlar

DOI
10.1515/znb-2000-1013

Iqtiboslar va manbalar

0 ta iqtibos0 ta foydalanilgan manba