Bis{N,N,N-trimethyl-2-oxo-2-[2-(2,3,4- trihydroxybenzylidene)hydrazinyl]ethanaminium} tetrachloridozincate(II) methanol solvate
Sladjana B. Novaković'Vinča' Institute of Nuclear Sciences, Laboratory of Theoretical Physics and Condensed Matter Physics, PO Box 522, 11001 Belgrade, SerbiaBojana M. Drašković'Vinča' Institute of Nuclear Sciences, Laboratory of Theoretical Physics and Condensed Matter Physics, PO Box 522, 11001 Belgrade, SerbiaLjiljana S. Vojinović‐JešićDepartment of Chemistry, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovića 3, 21000 Novi Sad, SerbiaValerija I. ČešljevićVinc ˇa' Institute of Nuclear Sciences , Laboratory of Theoretical Physics and Condensed Matter Physics , PO Box 522 , 11001 Belgrade , Serbia, andVukadin M. LeovacDepartment of Chemistry , Faculty of Sciences , University of Novi Sad , Trg Dositeja Obradovic ´a 3 , 21000 Novi Sad , Serbia
2010en
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The asymmetric unit of the title compound, (C(12)H(18)N(3)O(4))(2)[ZnCl(4)]·CH(3)OH, consists of two Girard reagent-based cations, a tetra-chlorido-zincate anion and a mol-ecule of methanol as solvate. These components are inter-connected in the crystal structure by an extensive network of O-H⋯O, N-H⋯O, C-H⋯O, O-H⋯N, O-H⋯Cl, N-H⋯Cl and C-H⋯Cl hydrogen bonds. The shortest inter-molecular inter-action is realized between the cation and anion [H⋯Cl = 2.29 (5) Å; O-H⋯Cl = 167 (3)°]. C-H⋯O inter-actions also play a important role in the inter-connection of the cations.
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